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The Potential Significance of Microwave-Assisted Catalytic Pyrolysis for Valuable Bio-Products Driven from Albizia Tree

Maha Faisal Abd, Atheer M. AL-yaqoobi

Abstract


The objective of this study is to investigate the feasibility of Na2CO3 and ZSM-5 as catalysts in the microwave pyrolysis of Albizia branches. An evaluation was conducted to determine the influence of power applied, experimental time, particle size, and catalysis type and ratio on the quality and quantity of pyrolysis products. Established methods such as GC-MS, FTIR, HHV, SEM, EDX, and BET were used to characterize the properties of bio-oil and biochar produced. The results demonstrated that using both catalyst types led to a substantial enhancement in biogas production. The improvement ranged from 5% to 41% with Na2CO3 and reached 45% with ZSM-5. At a lower power level of 300 W, the bio-oil yield augmented from 28% to 40% and 53% when using ZSM-5 and Na2CO3, respectively. The GC-MS analysis revealed that the utilizing of catalysts enhanced the levels of aromatic compounds, esters, and alcohols in bio-oil, along with an increase in the higher heating value (HHV) from 19.5 MJ/kg to 22 MJ/kg and 24.2 MJ/kg using Na2CO3 and ZSM-5, respectively. Moreover, the biochar's surface area and pore volume experienced a considerable rise, going from 0.5512 m2/g and 0.00011 cm3/g to a higher value of 115.2073 m2/g and 0.0774 cm3/g when treated with Na2CO3. The data indicated that both catalyst types enhanced the generation of CH4, and CO2 was lower with ZSM-5. The utilization of catalysts improves the quality of the biofuel produced and promotes the efficiency of the process in terms of energy consumption and processing time.

Keywords



[1]    A. M. Al-Yaqoobi, M. N. Al-Rikabey, and M. K. H. Al-Mashhadani, “Electrochemical harvesting of microalgae꞉ Parametric and cost-effectivity comparative investigation,” Chemical Industry & Chemical Engineering Quarterly, vol. 27, no. 2, pp. 121–130, 2021, doi: 10.2298/CICEQ191213031A.

[2]    S. A. Asongu, M. O. Agboola, A. A. Alola, and F. V. Bekun, “The criticality of growth, urbanization, electricity and fossil fuel consumption to environment sustainability in Africa,” Science of The Total Environment, vol. 712, 2020, Art. no. 136376, doi: 10.1016/j.scitotenv.2019.136376.

[3]    A. M. Al-Yaqoobi and M. N. Al-Rikabey, “Electrochemical Harvesting of Chlorella Sp.: Electrolyte Concentration and Interelectrode Distance,” Chemical Industry & Chemical Engineering Quarterly, vol. 29, no. 1, pp. 23–29, 2023, doi: 10.2298/CICEQ210815010A.

[4]    C. S. Dhanalakshmi, S. Kaliappan, H. M. Ali, S. Sekar, M. V. Depoures, P. P. Patil, B. S. Subbaiah, S. Socrates, and H. A. Birhanu, “Flash pyrolysis experiment on Albizia odoratissima biomass under different operating conditions: A comparative study on bio-oil, biochar, and noncondensable gas products,” Journal of Chemistry, vol. 2022, 2022, doi: 10.1155/2022/ 9084029.

[5]    B. A. Mohamed, C. S. Kim, N. Ellis, and X. Bi, “Microwave-assisted catalytic pyrolysis of switchgrass for improving bio-oil and biochar properties,” Bioresource Technology, vol. 201, pp. 121–132, 2016, doi: 10.1016/j.biortech. 2015.10.096.

[6]    A. S. Abbas and M. G. Saber, “Thermal and catalytic degradation kinetics of high-density polyethylene over NaX nano-zeolite,” Iraqi Journal of Chemical and Petroleum Engineering, vol. 17, no. 3, pp. 33–43, Sep. 2016, doi: 10.31699/ijcpe.2016.3.3.

[7]    A. N. M. A. Haque, M. Naebe, D. Mielewski, and A. Kiziltas, “Waste wool/polycaprolactone filament towards sustainable use in 3D printing,” Journal of Cleaner Production, vol. 386, Feb. 2023, Art. no. 135781, doi: 10.1016/j.jclepro. 2022.135781.

[8]    I. S. Ismail, M. F. H. Othman, N. A. Rashidi, and S. Yusup, “Recent progress on production technologies of food waste–based biochar and its fabrication method as electrode materials in energy storage application,” Biomass Conversion and Biorefinery, vol. 13, no. 16, pp. 14341–14357, Jan. 2023, doi: 10.1007/s13399-023-03763-3.

[9]    A. S. Abbas and S. D. A. Shubar, “Pyrolysis of high-density polyethylene for the production of fuel-like liquid hydrocarbon,” Iraqi Journal of Chemical and Petroleum Engineering, vol. 9, no. 1, pp. 23–29, Mar. 2008, doi: 10.31699/ijcpe.2008.1.4.

[10]  Nishu, R. Liu, Md. M. Rahman, M. Sarker, M. Chai, C. Li, and J. Cai, “A review on the catalytic pyrolysis of biomass for the bio-oil production with ZSM-5: Focus on structure,” Fuel Processing Technology, vol. 199, Mar. 2020,  Art. no. 106301, doi: 10.1016/j.fuproc.2019.106301.

[11]  M. J. Ahmed and S. K. Theydan, “Optimization of microwave preparation conditions for activated carbon from Albizia lebbeck seed pods for methylene blue dye adsorption,” Journal of Analytical and Applied Pyrolysis, vol. 105, pp. 199–208, Jan. 2014, doi: 10.1016/j.jaap.2013.11.005.

[12]  B. O. Adelawon, G. K. Latinwo, B. E. Eboibi, O. O. Agbede, and S. E. Agarry, “Comparison of the slow, fast, and flash pyrolysis of recycled maize-cob biomass waste, box-benhken process optimization and characterization studies for the thermal fast pyrolysis production of bio-energy,” Chemical Engineering Communications, vol. 209, no. 9, pp. 1246–1276, Jul. 2021, doi: 10.1080/00986445.2021.1957851.

[13]  A. S. Abbas and F. A. Mohamed, “Production and evaluation of liquid hydrocarbon fuel from thermal pyrolysis of virgin polyethylene plastics,” Iraqi Journal of Chemical and Petroleum Engineering, vol. 16, no. 1, pp. 21–33, Mar. 2015, doi: 10.31699/ijcpe.2015.1.3.

[14]  B. A. Mohamed, N. Ellis, C. S. Kim, X. Bi, and W.-H. Chen, “Engineered biochars from catalytic microwave pyrolysis for reducing heavy metals phytotoxicity and increasing plant growth,” Chemosphere, vol. 271, May 2021,   Art. no. 129808, doi: 10.1016/j.chemosphere.2021. 129808.

[15]  R. N. State, A. Volceanov, P. Muley, and D. Boldor, “A review of catalysts used in microwave assisted pyrolysis and gasification,” Bioresource Technology, vol. 277, pp. 179–194, Apr. 2019, doi: 10.1016/j.biortech.2019.01.036.

[16]  A. V. Bridgwater, “Review of fast pyrolysis of biomass and product upgrading,” Biomass and Bioenergy, vol. 38, pp. 68–94, Mar. 2012, doi: 10.1016/j.biombioe.2011.01.048.

[17]  A. Mamaeva, A. Tahmasebi, and J. Yu, “The effects of mineral salt catalysts on selectivity of phenolic compounds in bio-oil during microwave pyrolysis of peanut shell,” Korean Journal of Chemical Engineering, vol. 34, no. 3, pp. 672–680, Feb. 2017, doi: 10.1007/s11814-016-0291-3.

[18]  A. Doroshenko, I. Pylypenko, K. Heaton, S. Cowling, J. Clark, and V. Budarin, “Selective microwave‐assisted pyrolysis of cellulose towards levoglucosenone with clay catalysts,” ChemSusChem, vol. 12, no. 24, pp. 5224–5227, Nov. 2019, doi: 10.1002/cssc.201903026.

[19]  R. K. Liew, M. Y. Chong, O. U. Osazuwa, W. L. Nam, X. Y. Phang, M. H. Su, C. K. Cheng, C. T. Chong, and S. S. Lam, “Production of activated carbon as catalyst support by microwave pyrolysis of palm kernel shell: A comparative study of chemical versus physical activation,” Research on Chemical Intermediates, vol. 44, no. 6, pp. 3849–3865, Mar. 2018, doi: 10.1007/s11164-018-3388-y.

[20]  C. S. Dhanalakshmi and P. Madhu, “Utilization possibilities of Albizia amara as a source of biomass energy for bio-oil in pyrolysis process,” Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, vol. 41, no. 15, pp. 1908–1919, Nov. 2018, doi: 10.1080/15567036.2018.1549168.

 [21] M. F. Abd and A. M. Al-Yaqoobi, “The feasibility of utilizing microwave-assisted pyrolysis for Albizia branches biomass conversion into biofuel productions,” International Journal of Renewable Energy Development, vol. 12, no. 6, pp. 1061–1069, Oct. 2023, doi: 10.14710/ijred.2023.56907.

[22]  J. Lin, S. Sun, D. Xu, C. Cui, R. Ma, J. Luo, L. Fang, and H. Li, “Microwave directional pyrolysis and heat transfer mechanisms based on multiphysics field stimulation: Design porous biochar structure via controlling hotspots formation,” Chemical Engineering Journal, vol. 429, Feb. 2022, Art. no. 132195, doi: 10.1016/ j.cej.2021.132195.

[23]  Q. Bu, H. Lei, S. Ren, L. Wang, J. Holladay, Q. Zhang, J. Tang, and R. Ruan, “Phenol and phenolics from lignocellulosic biomass by catalytic microwave pyrolysis,” Bioresource Technology, vol. 102, no. 13, pp. 7004–7007, Jul. 2011, doi: 10.1016/j.biortech.2011.04.025.

[24]  A. Sharma, V. Pareek, and D. Zhang, “Biomass pyrolysis—A review of modelling, process parameters and catalytic studies,” Renewable and Sustainable Energy Reviews, vol. 50, pp. 1081–1096, Oct. 2015, doi: 10.1016/j.rser.2015. 04.193.

[25]  S. Liu, Y. Zhang, L. Fan, N. Zhou, G. Tian, X. Zhu, Y. Cheng, Y. Wang, Y. Liu, P. Chen, and R. Ruan, “Bio-oil production from sequential two-step catalytic fast microwave-assisted biomass pyrolysis,” Fuel, vol. 196, pp. 261–268, May 2017, doi: 10.1016/j.fuel.2017.01.116.

[26]  Y.-H. Seo, K.-H. Lee, and D.-H. Shin, “Investigation of catalytic degradation of high-density polyethylene by hydrocarbon group type analysis,” Journal of Analytical and Applied Pyrolysis, vol. 70, no. 2, pp. 383–398, Dec. 2003, doi: 10.1016/s0165-2370(02)00186-9.

[27]  X. Zhou, L. J. Broadbelt, and R. Vinu, “Mechanistic understanding of thermochemical conversion of polymers and lignocellulosic biomass,” Thermochemical Process Engineering, pp. 95–198, 2016, doi: 10.1016/bs.ache.2016.09.002.

 [28] G. Manos, A. Garforth, and J. Dwyer, “Catalytic degradation of high-density polyethylene over different zeolitic structures,” Industrial & Engineering Chemistry Research, vol. 39, no. 5, pp. 1198–1202, Mar. 2000, doi: 10.1021/ie990512q.

[29]  M. D. C. Rangel, F. M. Mayer, M. D. S. Carvalho, G. Saboia, and A. M. D. Andrade, “Selecting catalysts for pyrolysis of lignocellulosic biomass,” Biomass, vol. 3, no. 1, pp. 31–63, Jan. 2023, doi: 10.3390/biomass3010003.

[30]  J. Lin, S. Sun, J. Luo, C. Cui, R. Ma, L. Fang, and X. Liu, “Effects of oxygen vacancy defect on microwave pyrolysis of biomass to produce high-quality syngas and bio-oil: Microwave absorption and in-situ catalytic,” Waste Management, vol. 128, pp. 200–210, Jun. 2021, doi: 10.1016/j.wasman.2021.05.002.

[31]  L. Fan, R. Ruan, J. Li, L. Ma, C. Wang, and W. Zhou, “Aromatics production from fast co-pyrolysis of lignin and waste cooking oil catalyzed by HZSM-5 zeolite,” Applied Energy, vol. 263, Apr. 2020, Art. no. 114629, doi: 10.1016/j.apenergy.2020.114629.

[32]  B. A. Mohamed, X. Bi, L. Y. Li, L. Leng, E.-S. Salama, and H. Zhou, “Bauxite residue as a catalyst for microwave-assisted pyrolysis of switchgrass to high quality bio-oil and biochar,” Chemical Engineering Journal, vol. 426, Dec. 2021, Art. no. 131294, doi: 10.1016/j.cej.2021. 131294.

[33]  A. E. M. Fodah, M. K. Ghosal, and D. Behera, “Bio-oil and biochar from microwave-assisted catalytic pyrolysis of corn stover using sodium carbonate catalyst,” Journal of the Energy Institute, vol. 94, pp. 242–251, Feb. 2021, doi: 10.1016/j.joei.2020.09.008.

[34]  J. Lin, S. Sun, R. Ma, L. Fang, P. Zhang, J. Qu, X. Zhang, H. Geng, and X. Huang, “Characteristics and reaction mechanisms of sludge-derived bio-oil produced through microwave pyrolysis at different temperatures,” Energy Conversion and Management, vol. 160, pp. 403–410, Mar. 2018, doi: 10.1016/j.enconman. 2018.01.060.

[35]  H. Lei, S. Ren, and J. Julson, “The effects of reaction temperature and time and particle size of corn stover on microwave pyrolysis,” Energy & Fuels, vol. 23, no. 6, pp. 3254–3261, Apr. 2009, doi: 10.1021/ef9000264.

[36]  R. S. S. Prabhahar, P. Nagaraj, and K. Jeyasubramanian, “Promotion of bio oil, H2 gas from the pyrolysis of rice husk assisted with nano silver catalyst and utilization of bio oil blend in CI engine,” International Journal of Hydrogen Energy, vol. 45, no. 33, pp. 16355–16371, Jun. 2020, doi: 10.1016/j.ijhydene.2020.04.123.

 [37] O. R. Alara, N. H. Abdurahman, and C. I. Ukaegbu, “Extraction of phenolic compounds: A review,” Current Research in Food Science, vol. 4, pp. 200–214, 2021, doi: 10.1016/j.crfs.2021.03.011.

[38]  Z. Qiao, Z. Wang, C. Zhang, S. Yuan, Y. Zhu, J. Wang, and S. Wang, “PVAm–PIP/PS Composite Membrane with High Performance for CO2/N2 Separation,” AIChE Journal, vol. 59, no. 1, pp. 215–228, Mar. 2012, doi: 10.1002/aic.13781.

[39]  W.-H. Chen, C.-L. Cheng, K.-T. Lee, S. S. Lam, H. C. Ong, Y. S. Ok, S. Saeidi, A. K. Sharma, and T.-H. Hsieh, “Catalytic level identification of ZSM-5 on biomass pyrolysis and aromatic hydrocarbon formation,” Chemosphere, vol. 271, May 2021, Art. no. 129510, doi: 10.1016/ j.chemosphere.2020.129510.

[40]  C. A. Wallace, M. T. Afzal, and G. C. Saha, “Effect of feedstock and microwave pyrolysis temperature on physio-chemical and nano-scale mechanical properties of biochar,” Bioresources and Bioprocessing, vol. 6, no. 1, Sep. 2019, doi: 10.1186/s40643-019-0268-2.

[41]  J. Guo, L. Zheng, and Z. Li, “Comparative study of biochar properties and energy consumption derived from cow manure by a pilot-scale dual-function microwave and electric pyrolysis reactor,” Research Square, Aug. 2022, doi: 10.21203/rs.3.rs-1931004/v1.

[42]  T. Wang, H. Liu, C. Duan, R. Xu, Z. Zhang, D. She, and J. Zheng, “The eco-friendly biochar and valuable bio-oil from caragana korshinskii: pyrolysis preparation, characterization, and adsorption applications,” Materials, vol. 13, no. 15, Jul. 2020, Art. no. 3391, doi: 10.3390/ma13153391.

[43]  J. Yu, Z. Wu, X. An, F. Tian, and B. Yu, “Trace metal elements mediated co-pyrolysis of biomass and bentonite for the synthesis of biochar with high stability,” Science of the Total Environment, vol. 774, Jun. 2021, Art. no. 145611, doi: 10.1016/j.scitotenv.2021.145611.

[44]  C. Qian, Q. Li, Z. Zhang, X. Wang, J. Hu, and W. Cao, “Prediction of higher heating values of biochar from proximate and ultimate analysis,” Fuel, vol. 265, Apr. 2020, Art. no. 116925, doi: 10.1016/j.fuel.2019.116925.

[45]  A. E. M. Fodah, M. K. Ghosal, and D. Behera, “Quality assessment of bio-oil and biochar from microwave-assisted pyrolysis of corn stover using different adsorbents,” Journal of the Energy Institute, vol. 98, pp. 63–76, Oct. 2021, doi: 10.1016/j.joei.2021.06.008.

[46]  S. Y. Foong, N. S. Abdul Latiff, R. K. Liew, P. N. Y. Yek, and S. S. Lam, “Production of biochar for potential catalytic and energy applications via microwave vacuum pyrolysis conversion of cassava stem,” Materials Science for Energy Technologies, vol. 3, pp. 728–733, 2020, doi: 10.1016/j.mset.2020.08.002.

[47]  E. Yücedağ and H. Durak, “Bio-oil and bio-char from lactuca scariola: significance of catalyst and temperature for assessing yield and quality of pyrolysis,” Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, vol. 44, no. 1, pp. 1774–1787, Jul. 2019, doi: 10.1080/15567036.2019.1645765.

[48]  S. Li, S.-H. Ho, T. Hua, Q. Zhou, F. Li, and J. Tang, “Sustainable biochar as an electrocatalysts for the oxygen reduction reaction in microbial fuel cells,” Green Energy & Environment, vol. 6, no. 5, pp. 644–659, Oct. 2021, doi: 10.1016/ j.gee.2020.11.010.

[49]  M. Kamali, N. Sweygers, S. Al-Salem, L. Appels, T. M. Aminabhavi, and R. Dewil, “Biochar for soil applications-sustainability aspects, challenges and future prospects,” Chemical Engineering Journal, vol. 428, Jan. 2022, Art. no. 131189, doi: 10.1016/j.cej.2021. 131189.

[50]  A. K. Sakhiya, A. Anand, and P. Kaushal, “Production, activation, and applications of biochar in recent times,” Biochar, vol. 2, no. 3, pp. 253–285, May 2020, doi: 10.1007/s42773-020-00047-1.

[51]  J. Ahmad, F. Patuzzi, U. Rashid, M. Shahabz, C. Ngamcharussrivichai, and M. Baratieri, “Exploring untapped effect of process conditions on biochar characteristics and applications,” Environmental Technology & Innovation, vol. 21, Feb. 2021, Art. no. 101310, doi: 10.1016/ j.eti.2020.101310.

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DOI: 10.14416/j.asep.2024.07.016

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